Influence of component contents and structure characteristics of the components on heavy oils stability to asphaltene precipitation

Authors: L.М. Petrova, N. А. Abbakumova, D. N. Borisov, I.M. Zaidullin, Т.R. Foss, М.R. Yakubov, I.Sh. Khusnutdinov (A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre of RAS)

The study is aimed to investigate stability of heavy oil from Ashalchinskoye and Mordovo-Karmalskoye fields in regards to asphaltene precipitation. Microscopic observations intensity asphaltene precipitation by adding n-heptane to the oils were used. The asphaltene stability was investigated based on the optical density versus time of asphaltene toluene/n-heptane solutions by spectrophotometry. SARA analysis, gas-liquid chromatography and FTIR spectroscopy were used to characterize the heavy oils components.
Key words: oil stability, asphaltenes, spectrophotometry, Fourier transmission infra-red spectroscopy (FTIR)

List of references

1. Akbarzade K., Khammadi A., Kharat A. et al. Neftegazovoe obozrenie, 2007, T. 19, no. 2, pp . 28-53.

2. Takhautdinov Sh.F., Khisamov R.S., Ibatullin R.R., et al. Geologicheskie i tekhnologicheskie osobennosti razrabotki zalezhi sverkhvyazkoy nefti Ashal'chinskogo mestorozhdeniya (Geological and technological challenges of development of heavy oil reservoir in Ashalchinskoye field). Neftyanoe khozyaystvo – Oil Industry, 2009, no.7, pp. 34-37.

3. Zaripov A.T., Ibatullina S.I., Motina L.I., Khisamov R.S. Tekhniko-ekonomicheskaya otsenka metodov razrabotki prirodnykh bitumov dlya usloviy mestorozhdeniy Respubliki Tatarstan (Technical and economic estimation of methods of natural bitumens development for conditions of Republic Tatarstan). Neftyanoe khozyaystvo – Oil Industry, 2006, no.3, pp. 64-66.

4. Rakhimova Sh.G., Amerkhanov M.I., Khisamov R.S. Vozmozhnosti ispol'zovaniya neftyanykh rastvoriteley v tekhnologiyakh paroteplovogo vozdeystviya (Capabilities of petroleum solvents use in technologies of thermal-steam treatment). Neftyanoe khozyaystvo – Oil Industry, 2009, no. 2, pp. 101-103.

5. Ibatullin T.R. Povyshenie effektivnosti tekhnologii parogravitatsionnogo vozdeystviya s primeneniem uglevodorodnykh rastvoriteley (Steam Assisted Gravity Drainage enhancement using hydrocarbon solvents). Neftyanoe khozyaystvo – Oil Industry, 2008, no. 10, pp. 74-76.

6. Comparisons between Open Column Chromatography and HPLC SARA Fractionations in Petroleum. C.A. Islas-Flores, E. Buenrostro Gonzalez, C. Lira-Galeana, Energy & Fuels, 2005, V. 19, pp. 2080-2088.

7. A Study of Asphaltene Solubility and Precipitation. E. Hong, P. Watkinson, Fuel, 2004, V. 83, pp. 1881-1887.

8. Properties of Resins Extracted from Boscan Crude Oil and Their Effect on the Stability of Asphaltenes in Boscan and Hamaca Crude Oils. N.F. Carnahan, J.-L. Salager, R. Ant′on, A. D′avila, Energy & Fuels, 1999, no. 13, pp. 309-314.

9. Electrodeposition of Asphaltenes. 2. Effect of Resins and Additives. D.S. Khvostichenko, S.I. Andersen, Energy & Fuels, 2010, no.24, pp. 2327–2336.

10. Characterization of Polarity-Based Asphaltene Subfractions. P. Wattana, H.S. Fogler, A. Yen, M.C. Garc′ia, L. Carbognani, Energy & Fuels, 2005, no. 19, pp. 101-110.

11. Asphaltene Stability in Crude Oils. E. Rogel, O. Leon, Y. Espidel, Y. Gonzalez, U. Metropolitana, SPE Production & Facilities, 2001, V. 16, no. 2, pp. 84-88.

12. Asphaltene Deposition Prediction and Control in a Venezuelan North Monagas Oil Field. G.M. Carcia, M. Henriquez , International Symposium on Oilfield Chemistry, 5-7 February 2003, Houston, Texas.

13. Characterization of fractionated asphaltenes by UV–vis and NMR self-diffusion spectroscopy. J.-A. Tsstlund, P. Wattana, M. Nydyn, H.S. Fogler, Journal of Colloid and Interface Science, 2004, no.271, pp. 372-380.



Attention!
To buy the complete text of article (Russian version a format - PDF) or to read the material which is in open access only the authorized visitors of the website can. .