There are given the results of studies of phosphonic complexons influence on deposition of salts from aqueous solutions comprising deposit generating ions. The possibility of their application as inhibitors of poorly soluble salts crystallization is evaluated. It is established that application of polymer additives together with phosphonic complexons increases the efficiency of scale inhibition. The prospects of chemical scale prevention methods are shown.
References
1. Krabtri M., Eslinger D., Fletcher F. et al., Prevention of salts - removal and prevention of their formation (Transl. to Russ.), Neftegazovoe obozrenie, 2002, Autumn, pp. 52–73.
2. Richardson S.M., McSween H.Y., Geochemistry: pathways and processes,
Englewood Cliffs, New Jersey, USA: Prentice-Hall, Inc., 1989, рр. 72–81.
3. Lyushin S.Yu., Glazkov A.A., Galeeva G.V. et al., Otlozheniya neorganicheskikh soley v skvazhinakh, prizaboynoy zone plasta i metody ikh predotvrashcheniya (Deposition of inorganic salts in wells, bottomhole formation zone and how to avoid them): overview, Moscow: Publ. of VNIIOEG, 1983, V. 11, 100 p.
4. Marinin N.S., Yaryshev G.M., Mikhaylov S.A. et al., Metody bor'by s otlozheniem soley (Methods of prevention the salt deposits): overview, Moscow: Publ. of VNIIOEG, 1980. – 55 s.
5. Dyatlova N.M., Temkina V.Ya., Popov K.I., Kompleksony i kompleksonaty metallov (Complexones and metal complexonates), Moscow: Khimiya Publ., 1988, 544 p.
6. Pereyma A.A., Regulirovanie svoystv tamponazhnykh rastvorov kombinirovannymi reagentami na osnove fosfonovykh kompleksonov (Regulation of properties of cement slurries by combined reagents based on phosphonic complexons), Proceedings of VNIIgaz, Moscow: Publ. of VNIIgaz, 1993, pp. 22–27.
7. Certificate of authorship no. 1839040 CCCP, MPK6 E 21 V 33/138, Kompleksnyy reagent dlya tamponazhnykh rastvorov na osnove portlandtsementa (Complex reagent for cement slurries based on Portland cement), Authors: Pereyma A.A., Pertseva L.V., Petrakov Yu.I., Il'yasov V.I., Gusmanov R.A., Yakovenko N.A.
8. Certificate of authorship no. 1839039 CCCP, MPK6 E 21 V 33/138. Kompleksnyy reagent dlya tamponazhnykh rastvorov na osnove shlakovykh
vyazhushchikh (Complex reagent for cement slurries based on slag binders),
Author: Pereyma A.A.
9. Pereyma A.A., Gasumov R.A., Tenn R.A. et al., Investigation of the influence of phosphonic complexing on process of crystallization of poorly soluble salts (In Russ.), Proceedings of VNIIgaz, SevKavNIPIgaz, Moscow: Publ. of VNIIgaz, 1999, pp. 89–93.
10. Patent no. 2059058 RF, MPK6 E 21 V 33/138, S 04 V 38/02, Gas-cement
compound, Inventors: Pereyma A.A., Tagirov K.M., Il'yaev V.I.
11. Pereyma A.A., Razrabotka tamponazhnykh materialov i tekhnologicheskikh zhidkostey dlya zakanchivaniya i remonta skvazhin v slozhnykh gornogeologicheskikh usloviyakh (Development of cementing materials and technological liquids for completion and workover wells in hard geological conditions): Thesis of doctor of technical science, Krasnodar, 2009.
12. Nancollas G.H., Kazmierczak T.F., Schuttringer E.A., Controlled composition study of calcium carbonate growth: the influence of scale inhibitors, Corrosion, NACE 37, 1981, no. 2, pp. 76–81.
13. Powell R.J., Fischer A.R., Gdanski R.D. et al., Encapsulated scale inhibitor for use in fracturing treatments, SPE 30700,1995.
